Overriding A System.xml file for adding addition settings to an exist module in a new module. Module name is (Namespace_Modulename) Note : Change as per requirement like change groupname,sectionname,fieldname.
Then after for saving these datas into database.Go to register.phtml (Path can be :- app/design/frontend/default/bootstrap/template/opc/customer/form/register.phtml
In billing.phtml -> paste below code in billing.phtml at just below at already had email field. Then open validation.js which is located at js/prototype/validation.jsand paste below code at just below the line => return !(pass.length < 7)